Mold on top, or it is fermenting
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The three causes
Three things produce this and they are not equally likely, which matters because the usual response is to blame the seal when the seal is rarely the problem. Two of the three happen before the jar is ever closed.
- Yeasts and mold growing on the product, which is what too much free water allows.
- Imperfect sealing, which lets them in.
- Improper storage, which lets them work.
Why the sugar concentration is the first defense
The 65 percent figure is not only about texture. A solution that concentrated is hostile to most of what would otherwise grow in it, which is why the percentage is specified rather than recommended and why cutting it to make a lighter product changes the keeping qualities as well as the taste.
The 65 percent figure in the standard is doing this job as well as holding the gel. A product below concentration has water available, and then the seal and the storage are all that is left between it and spoilage. That is on 65 percent soluble solids.
The bubbles warning
Rising bubbles in a sealed jar are the signal that separates a cosmetic problem from one that means the jar does not get sold. They are worth looking for deliberately rather than noticing by accident. Hold a jar up to a window and look at the body of the set rather than the surface, because the surface is where the cosmetic case lives and the body is where the other one shows.
What not to do
The instinct when a jar has mold on top is to deal with the mold, and that is the one response the published guidance is unambiguous about.
Do not scrape mold off and keep the rest. The visible growth is not the extent of it, and a jar that has gone is a jar that has gone.