Buy a full case and the price per unit drops automaticallyRequest a sample
AccountCart0
All ContainersBottlesJarsCaps & ClosuresPumps & SprayersTubs & PailsJugsDroppersTinsTubesAccessories
Industries
Learn
What goes wrong

Efflorescence and Byne's disease

Updated

On this page5

A white crystalline crust on calcareous specimens, and it is a symptom of the cabinet rather than of the stone.

A white bloom that is not dust

A fine white powder or crust, sometimes fluffy, on calcite, aragonite, shells and other carbonate material. It wipes off and comes back.

Under magnification it is crystalline. It is growing, and it is growing out of the specimen.

What is actually happening

Acid vapor in the air reacts with calcium carbonate at the specimen surface, forming calcium acetate and calcium formate salts. Those salts crystallize as the efflorescence you can see.

Named Byne's disease in the shell-collecting literature, which is where it was first described and where the guidance is best documented. It is a chemical attack rather than a disease, and the name has stuck.

The reaction needs moisture, so high relative humidity accelerates it and controlling humidity is most of the defense.

It is destructive: material is being converted and lost, not merely coated.

Where the acid comes from

This is the part that surprises people. The acid is usually produced by the storage.

Wood. Oak is notorious. Cabinets, drawers and drawer liners emit acetic and other carboxylic acids as they age.

Adhesives, coatings and sealants used in cabinet construction.

Degrading plastics. PVC emits acidic products as it breaks down, acetic acid chief among them, along with hydrochloric and formic acid.

A decaying pyrite specimen in the same enclosed space.

So a collector who buys a handsome old wooden cabinet has bought an acid source and put the collection inside it.

Fixing it, and preventing it

Remove the specimen from the source. That is the fix; everything else is cosmetic.

Brush the efflorescence off dry, gently. Washing carbonates is a decision to take carefully.

Then address the enclosure: inert plastic rather than PVC, sealed or barrier-coated wood, good air exchange rather than a tightly closed drawer, and humidity held moderate.

And separate sulfides from carbonates, because one of them produces what attacks the other.

References

US National Park Service. Conserve O Gram 11/15, Byne's "Disease". Acid vapor reacting with calcium carbonate to form calcium acetate and formate efflorescence, accelerated by high relative humidity. nps.gov
Canadian Conservation Institute. Caring for natural history collections, preventive conservation guidelines. Covers relative humidity, harmful volatiles emitted by cabinet materials, and the specimens most at risk from each. canada.ca
Research on poly(vinyl chloride) degradation in heritage collections: PVC emits acidic degradation products, with acetic acid identified as the main compound responsible for damage, alongside hydrochloric and formic acid. npj Heritage Science
Natural Sciences Collections Association. Care and Conservation of Geological Specimens. Storage environment, materials and the named decay mechanisms. natsca.org
Written from the federal land-management rules, the conservation literature and the agency guidance named on each page. Collecting rules differ by agency, by unit and sometimes by parcel, and the land manager for the ground you are standing on is the authority on it, not this page.