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The pH check on a cultured product

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For a yogurt this is not a quality check, it is the measurement the standard of identity names, with a time window attached.

Calibrate every session

Meters drift and buffers age. This is the measurement that decides whether your product meets the standard it is labeled against, so calibrate against fresh buffers before the readings that matter rather than at the start of a season.

Measure the finished product, within 24 hours of filling

The standard specifies a pH of 4.6 or lower measured on the finished product within 24 hours after filling. That means the measurement is taken on what is in the container, in the window named, rather than on the vat before filling.

Measure it cold, consistently

Temperature affects the reading, so take it at a consistent temperature and record which. A reading taken warm on one batch and cold on the next produces a difference that has nothing to do with the fermentation.

Use it as the endpoint, not only as a check

The real value is deciding when the fermentation is finished rather than confirming afterwards that it was. Finishing on the number instead of the clock removes the largest source of batch-to-batch variation in the craft.

Record it against the batch

The reading, the time after filling, the temperature, the meter and the batch code. That record is what supports the name on the label, and a number remembered is a recollection.

If it did not reach the number

It is not yogurt as the standard defines it, and that does not change by taking a second reading later. It may be a perfectly good cultured milk product under a different name, and that is the honest route rather than relabeling the measurement.

Clean the probe properly, every time

Milk protein and fat foul a glass electrode quickly and a fouled probe reads slowly and wrongly. Rinsing and the occasional proper clean is the difference between a meter you can trust and one that quietly drifts through a season of readings.

References

21 CFR 131.200, Yogurt: not less than 3.25 percent milkfat and not less than 8.25 percent milk solids not fat, with “a pH of 4.6 or lower measured on the finished product within 24 hours after filling.” law.cornell.edu
21 CFR 114, Acidified Foods, whose 114.3 definition turns on a finished equilibrium pH of 4.6 or below, the same figure the yogurt standard uses. law.cornell.edu
Written from federal regulation and FDA guidance, not from a laboratory. Pasteurization of milk and milk products in final package form for interstate commerce is a federal requirement, and what your state permits inside its own borders is a separate question. Anything here is a starting point for a conversation with your state department of agriculture, not a determination that you comply.