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What goes wrong

Humidity, high and low

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Relative humidity is a consequential thing about a room full of minerals, and it is pulled in two directions at once.

One number, two opposite failures

Some species fail when it is high. Others fail when it is low. There is no setting that suits everything, which is why a mixed collection is a compromise and the rarities get their own boxes.

Too high

Pyrite and other sulfides oxidize, expanding and producing sulfuric acid. Above about 60% RH this proceeds; the recommendation is to stay at or below 45%.

Efflorescence on carbonates accelerates, because the reaction with acid vapor needs moisture.

Soluble species dissolve or deliquesce. Halite and several others take up water from the air and slump.

Mold and pests reach anything organic in the storage: labels, card, wooden mounts.

Too low

Hydrated minerals lose water. Borax, chalcanthite, laumontite and others dehydrate, going cloudy or white and crumbling. Laumontite is the classic case and it can happen within months.

Clays and some matrices shrink and crack.

Dehydration is usually irreversible, which makes it the more permanent of the two failures.

Where to set it

Around 45 to 50% suits the majority: low enough to hold sulfides, high enough not to dehydrate most hydrates.

Then treat the exceptions individually. Susceptible sulfides in sealed boxes with conditioned silica gel held low; known hydrates in sealed boxes held higher, or with a damp buffer.

Stability matters more than the exact number. A collection at a steady 55% is in better shape than one cycling between 35 and 65, because each swing moves water in and out of the specimens.

Which means the practical answer for many collectors is an interior room rather than a garage, a basement or an attic, and a cheap hygrometer, read occasionally, so you know what you actually have.

Finishes that will hold a seal

A lined cap is ordered against that number, and the liner is what holds the humidity.
PET Single Wall Jar
1 fl oz · 38-400 · PET · to 120F
38-400 finish.
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16 oz Clear 25% PCR PET Single Wall Jar
16 fl oz · 89-400 · PET · to 120F
89-400 finish.
$0.47
each
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PET Single Wall Jar
4 fl oz · 58-400 · PET · to 120F
58-400 finish.
$0.55
each
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2 oz Amber PET Single Wall UV Protection Jar
2 fl oz · 48-400 · PET · to 120F
48-400 finish.
$0.57
each
See it

References

Canadian Conservation Institute. Caring for natural history collections, preventive conservation guidelines. Covers relative humidity, harmful volatiles emitted by cabinet materials, and the specimens most at risk from each. canada.ca
Canadian Museum of Nature. Pyrite disease. Pyrite oxidizes in the presence of oxygen at elevated relative humidity, expanding into iron sulfates and producing sulfuric acid that attacks labels and storage materials alongside the specimen. nature.ca
Natural Sciences Collections Association. Care and Conservation of Geological Specimens. Storage environment, materials and the named decay mechanisms. natsca.org
Written from the federal land-management rules, the conservation literature and the agency guidance named on each page. Collecting rules differ by agency, by unit and sometimes by parcel, and the land manager for the ground you are standing on is the authority on it, not this page.