The chemistry exception
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What it permits
Glass or plastic containers of not more than one gallon for a Category 1 or 2 flammable liquid, which is up from a pint and a quart in Table H-12.
Condition one, the chemistry
That the liquid "either would be rendered unfit for its intended use by contact with metal or would excessively corrode a metal container so as to create a leakage hazard".
Read both halves of that
Either the metal ruins the liquid, or the liquid ruins the metal. The first covers a reagent or a finish contaminated by metal ions; the second covers an acid or a halogenated solvent attacking the can.
Condition two, the quantity your process needs
More than one pint of a Category 1 liquid, or more than one quart of a Category 2 liquid, of a single assay lot at one time. The exception is for a process that genuinely cannot work within the table.
Or an analytical standard
Where maintaining a standard liquid of a quality not met by available standard liquids needs a quantity exceeding one sixteenth of the capacity the table allows for that category. A laboratory provision rather than a shop one.
And a separate export route
The paragraph also permits such containers where they "are intended for direct export outside the United States", which has nothing to do with chemistry and sits in the same place.
Why this is the most useful paragraph in the property
Because the reason to choose glass over metal is the same reason the regulation allows it. A liquid that cannot be stored in metal is a liquid this shelf can serve to a gallon.
Both conditions, not either
The chemistry and the process quantity. Needing a gallon is not enough and the liquid attacking metal is not enough; the exception asks for the two together.
Document which one applies
Not for us, for the inspector. The exception is a determination about your liquid and your process, and the file is the only evidence it was made.
And the approval question does not go away
(d)(2)(i) still says only approved containers shall be used. The exception raises a capacity ceiling; it does not tell you that a particular bottle is an approved container.