Selling a decant
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A water-based acrylic decant travels
It is not a flammable liquid, it is not pressurized, and a lined cap in a padded box arrives intact. This is the straightforward case and most of the craft is in it.
A solvent-borne one is a different shipment
A flammable liquid in a parcel network carries packaging, marking and training requirements of its own under the hazardous materials rules. Those are not satisfied by a sturdy box.
And the classification is a measurement
Extremely flammable at or below 20 degrees F, flammable above that and below 100 degrees F, by the method at 16 CFR 1500.43a. The number comes from the carrier liquid rather than from the paint's name.
Carriers have their own limits
Separate from the regulations and often stricter, with their own approvals and surface-only restrictions. Ask before designing the product around a shipping method.
Which is why the format question is a business question
A decanted lacquer may be a fine product and an uneconomic one to ship. Finding that out after the bottles arrive is the expensive order to do it in.
A convention table removes the carrier and not the label
Handing a bottle to somebody in person is still marketing a substance for making art. The labeling obligation does not depend on the channel.
Breakage changes the glass calculation
Glass is the right resin for a solvent and the wrong material for a parcel network. That tension is real and it usually resolves as glass for the bench and water-based products for the post.
Batch records earn their keep here
Which bottle, which drum, which label version, which date. A problem in one batch is a recall of one batch if you can tell them apart and of everything if you cannot.
And the twelve-month clock runs on the label you keep reordering
New hazard information has to reach material manufactured after twelve months from discovery. A standing print order is the mechanism by which that gets missed.
The honest summary
Water-based decants are a sellable product with a labeling obligation. Solvent-borne decants are a bench practice that becomes a regulated shipment the moment you sell one.