PVC, and why it is named
On this page9
The statement
"Do not use office quality paper, kraft paper, plastics containing PVC, or glassine enclosures." Four named materials to avoid, and PVC is the plastic among them.
Why PVC is the problem
It is plasticised to stay flexible, and the plasticiser migrates out over time. What it migrates onto is whatever the plastic is touching, which in this craft is a coin or a stamp.
Collectors know the symptom
The green film on a coin that has sat in a soft flexible holder for years. It is the plasticiser and the degradation products of the PVC itself, and removing it is a conservation job rather than a wipe.
And it degrades to something acidic
Deteriorating plastics emit acidic vapours, which is why a metal coupon is used to detect an off-gassing plastic: the metal corrodes. In a sealed jar there is nowhere for those vapours to go.
It keeps appearing because it is cheap and clear
Soft, flexible, transparent, inexpensive. Everything a collector wants from a holder, which is exactly why the bad holders are so common.
This catalog holds very little of it
52 PVC items across 2,150 products, and 50 of them are shrink bands, sleeves and bags. The other two are an f-style bottle and a cylinder. Nothing on this shelf is PVC.
But do not shrink-band a collection jar
The one PVC product a collector might plausibly reach for here is a shrink band for tamper evidence, and putting a PVC film around the mouth of a jar that is meant to hold metal for decades is the one thing on this page to avoid.
How to tell
Ask the supplier for the material. For a holder already in a collection, the soft, floppy, slightly oily ones are the suspects and the rigid ones usually are not. If in doubt, move the object.