Below one milliliter
Updated
On this page8
What it says
When packaged in accordance with the section, the listed materials do not meet the definition of a hazardous material in 49 CFR 171.8 and are therefore not subject to the requirements of the subchapter. That is a stronger statement than an exception.
The classes it covers
Packing Group I materials of Division 6.1 with no inhalation hazard, and Packing Group II and III materials of Class 3, Divisions 4.1, 4.2, 4.3 and 5.1, Division 6.1, Class 8 and Class 9. Ethanol’s class is on that list.
The quantity
One milliliter per inner receptacle for authorized liquids, one gram for solids. That is a vial, not a jar, and it is realistic only for very small preserved material or for a sample of the fluid itself.
The closure restraint again
Each inner receptacle with a removable closure has its closure held securely in place with wire, tape, or other positive means. The same sentence appears in both sections, which tells you how much weight it carries.
And a tougher package test
Five free drops from 1.8 m, which is 5.9 feet, onto a solid unyielding surface: flat on bottom, flat on top, flat on the long side, flat on the short side, and on a corner at the junction of three intersecting edges. Plus a compressive load.
Without breakage or leakage from any inner receptacle
And without a substantial reduction in the effectiveness of the package. So the outer packaging is doing real work, and the glass vial inside is surviving because of what is around it.
Which route fits depends on the collection
A single small type specimen might travel under 173.4b. A set of jars does not fit either section, and then the answer is a properly classified shipment rather than an exception, which is a question for a hazmat shipper.