Shipping a flammable liquid
Updated
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What the exception gives you
Limited quantities of Class 3 flammable liquids are excepted from labeling requirements, unless offered by aircraft, and excepted from the specification packaging requirements when packaged in combination packagings according to the paragraph.
And it goes further
A conforming limited quantity package is not subject to the shipping paper requirements of subpart C, unless the material is a hazardous substance, hazardous waste or marine pollutant or is going by aircraft or vessel, and shipments are not subject to placarding.
The inner packaging limits
For Packing Group I, inner packagings not over 0.5 L each. For Packing Group II, not over 1.0 L each. For Packing Group III and combustible liquids, not over 5.0 L each. In every case packed in a strong outer packaging.
And a cap on the whole package
Each package must conform to the packaging requirements of subpart B and may not exceed 30 kg, which is 66 pounds, gross weight. For 30 mL bottles that is not a practical constraint; for a case of 120 mL bottles in glass it can be.
Your packing group follows from the flash point
Which follows from the concentration. So the inner limit you are working to is a consequence of the formula, and a reformulation upward can move you into a tighter limit without anything else changing.
Air is a different answer
For transportation by aircraft the package must also conform to 49 CFR 173.27, including authorized materials, inner packaging quantity limits and closure securement, and only hazardous material authorized aboard passenger-carrying aircraft may go as a limited quantity.
And the exception is not automatic
It is permitted only if 173.150 is referenced for the specific hazardous material in the 172.101 table. So the first step is the table entry for what you are actually shipping, not the exception itself.